COPOLÍMEROS HIDROSOLUBLES CON ALTA DENSIDAD DE URETANO

Borja Fernández-d'Arlas Bidegain; Ricardo Arpad Pérez-Camargo; Jordana K Palacios; Alejandro J Müller

doi:10.5281/zenodo.7213651

HYDROSOLUBLE COPOLYMERS WITH HIGH URETHANE DENSITY

Authors

Borja Fernández-d'Arlas Bidegain Evolgene Genómica S.L, Avenida de Tolosa 76, E-20018, San Sebastián, España
Ricardo Arpad Pérez-Camargo Laboratorio Nacional de Pekín para Ciencias Moleculares, Laboratorio de Ingeniería del Plástico, Instituto de Química.13 Academia China de las Ciencias. Pekín, 100190, China
Jordana K Palacios Fundación Centro Tecnológico Miranda de Ebro (CTME), Departamento de I+D Materiales, Miranda de Ebro, 09200, 15 Burgos, España
Alejandro J Müller POLYMAT y Departamento de Polímeros y Materiales Avanzados: Física, Química y Tecnología, Facultad de Química, Universidad del País Vasco UPV/EHU, Paseo Manuel de Lardizabal 3, 20018, Donostia-San Sebastián, España

DOI:

https://doi.org/10.5281/zenodo.7213651

Abstract

With the aim of mimicking silks physico-chemical properties, here we developed urethane copolymers based on semi-crystalline segments formed by hexamethylene diisocyanate (HDI) and ethylen glycol (EG), and quaternizable amorphous segments formed by HDI and methylene diethanolamine (MDEA). The polyurethane (PU) amorphous segments provide water solubility in aqueous media upon MDEA quaternization, once the ratio between crystalline to amorphous segments is lower than 4. In the presence of salts, these PUs follow an inverse Hofmeister series, which has been used to synthesize fibers based on the kosmotropic phenomena, analogous to silk fibers formation in nature. These polymers have the potential to be used as waterborne adhesives or drugs encapsulating agents.

Downloads

Download data is not yet available.

Author Biography

Borja Fernández-d'Arlas Bidegain, Evolgene Genómica S.L, Avenida de Tolosa 76, E-20018, San Sebastián, España

Polímeros; Poliuretanos; Composites; Materiales poliméricos; Sedas; Poliamidas; Queratinas

COPOLÍMEROS HIDROSOLUBLES CON ALTA DENSIDAD DE URETANO Borja Fernández-d’Arlas, Ricardo Arpad Pérez-Camargo, Jordana K. Palacios, Alejandro J. Müller

Downloads

pdf (Español (España))

Published

2022-07-02 — Updated on 2022-10-24

How to Cite

Fernández-d’Arlas Bidegain, B., Pérez-Camargo, R. A., Palacios, J. K., & Müller, A. J. (2022). HYDROSOLUBLE COPOLYMERS WITH HIGH URETHANE DENSITY. LatinAmerican Journal of Metallurgy and Materials, 42(1), 20–40. https://doi.org/10.5281/zenodo.7213651

Download Citation

Issue

2022, 42(1)

Section

Regular Articles

License

The authors of papers accepted for publication by the RLMM, should recognize the complete transfer of copyright (in all languages) to the RLMM. This transfer includes the right by the RLMM to adapt the article for digital or printed reproduction without altering the written content and information displayed in tables or figures within. The authors retain the copyright and guarantee the journal the right to be the first publication of the work as well as licensed under a Creative Commons Attribution License 4.0 Internacional (CC BY 4.0) which allows others to share the work with an acknowledgment of the authorship of the work and the initial publication in this journal.